{"id":6459,"date":"2026-07-12T13:50:22","date_gmt":"2026-07-12T05:50:22","guid":{"rendered":"https:\/\/woodrefinery.com\/zhenfang\/?p=6459"},"modified":"2026-07-12T13:50:22","modified_gmt":"2026-07-12T05:50:22","slug":"%e5%a1%91%e6%96%99%e5%88%b6%e7%83%b7%e5%9f%ba%e8%8a%b3%e7%83%83coupling-polyolefin-conversion-and-methanol-reduction-for-c9-c10-alkylaromatic-production","status":"publish","type":"post","link":"https:\/\/woodrefinery.com\/zhenfang\/%e5%a1%91%e6%96%99%e5%88%b6%e7%83%b7%e5%9f%ba%e8%8a%b3%e7%83%83coupling-polyolefin-conversion-and-methanol-reduction-for-c9-c10-alkylaromatic-production\/","title":{"rendered":"\u5851\u6599\u5236\u70f7\u57fa\u82b3\u70c3Coupling Polyolefin Conversion and Methanol Reduction for C9-C10 Alkylaromatic Production"},"content":{"rendered":"

Coupling Polyolefin Conversion and Methanol Reduction for C9<\/sub>-C10<\/sub>\u00a0Alkylaromatic Production<\/span><\/strong><\/p>\n

\u00a0 Recently, under the supervision of Professor Zhen Fang<\/strong>, collaborated with Profs. Richard L. Smith (Tohoku Univ, Japan) and Janusz Kozinski (Lakehead Univ, Canada), PhD student Mr. Sheng-ren Li published a research article focusing on polyolefin conversion into C9<\/sub>-C10<\/sub>\u00a0Alkylaromatic in\u00a0Angewandte Chemie International Edition\u00a0<\/em>(Q1; Impact factor: 17.6).<\/span><\/p>\n

\u00a0 This work presents a strategy for integrating polyethylene (PE) aromatization and Friedel\u2013Crafts-type alkylation reactions via methanol reduction for upgrading PE to 79.0 wt% liquid with 56.1 wt% aromatics at 280 \u00b0C, enabled by a bifunctional NiGa\/ZSM-5-H catalyst. In the catalyst design, hierarchical ZSM-5-H promotes cracking of PE, while Ga serves not only as an active site for aromatization and alkylation, but also suppresses Ni\u2070 formation by withdrawing electron density from Ni, ensuring that Ni2+<\/sup>\u00a0remains as the active catalytic site for methanol reduction. Hydrogen species derived from PE aromatization participate in methanol reduction, while methanol functions mainly as a hydrogen sink and methyl donor yet also releases some hydrogen under reaction conditions, allowing the PE aromatization and methanol reduction steps to be coupled. In the presence of hydrogen, methanol reduction generates methyl species that promote Friedel\u2013Crafts-type alkylation, incorporating methyl groups into the alkyl substituents of aromatics and boosting C9<\/sub>-C10\u00a0<\/sub>alkylaromatics yields by more than 600%. By introducing 0.99 g\/g methanol equivalent into the PE-catalyst reaction system, aromatic and C9<\/sub>-C10\u00a0<\/sub>alkylaromatics yields are more than double those without methanol. The strategy is applicable to upgrading of polyolefins and offers a practical route for industrial processing of plastic waste.<\/span><\/p>\n

\u00a0 Results were accepted in Angewandte Chemie International Edition<\/em><\/span>\uff1a<\/p>\n

\n

SR Li, RL. Smith, JA Kozinski,\u00a0Zhen Fang*<\/strong>, Coupling Polyolefin Conversion and Methanol Reduction for C9<\/sub>-C10<\/sub>\u00a0Alkylaromatic Production, Angewandte Chemie International Edition,\u00a02026<\/strong>, e5589662,\u00a0https:\/\/doi.org\/10.1002\/anie.5589662<\/a>.<\/span><\/strong><\/span><\/p>\n

\"\"<\/p>\n

\u805a\u70ef\u70c3\u8f6c\u5316\u4e0e\u7532\u9187\u8fd8\u539f\u8026\u8054\u751f\u4ea7C9-C10<\/span>\u70f7\u57fa\u82b3\u70c3Coupling Polyolefin Conversion and Methanol Reduction for C9-C10 Alkylaromatic Production<\/span><\/p>\n

\n<\/div>\n

\u535a\u58eb\u751f\u674e\u80dc\u4efbAngew: \u805a\u70ef\u70c3\u8f6c\u5316\u4e0e\u7532\u9187\u8fd8\u539f\u8026\u8054\u751f\u4ea7<\/strong>C9<\/sub>-C10<\/sub><\/span><\/strong>\u70f7\u57fa\u82b3\u70c3<\/strong><\/p>\n

\u00a0 \u6700\u8fd1\uff0c\u5728\u65b9\u771f\u6559\u6388<\/strong>\u7684\u6307\u5bfc\u4e0b\uff0c\u4e0e\u65e5\u672c\u4e1c\u5317\u5927\u5b66Richard L. Smith<\/span>\u6559\u6388\u548c\u52a0\u62ff\u5927\u6e56\u9996\u5927\u5b66Janusz Kozinski<\/span>\u6559\u6388\u5408\u4f5c\uff0c\u535a\u58eb\u751f\u674e\u80dc\u4efb\u5728\u300aAngewandte Chemie International Edition\u300b(Q1; Impact factor: 17.6)\u00a0<\/span>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u805a\u70ef\u70c3\u5851\u6599\u5347\u7ea7\u5236\u5907\u9ad8\u4ef7\u503cC9<\/sub>-C10<\/sub><\/span>\u70f7\u57fa\u82b3\u70c3\u7684\u7814\u7a76\u6027\u8bba\u6587\u3002\u8fd9\u662f\u674e\u80dc\u4efb\u540c\u5fd7\u4e00\u4f5c\u53d1\u8868\u5173\u4e8e\u6db2\u5316\u7684\u7b2c3\u7bc7\u8bba\u6587\uff08\u6b64\u524d\u5728CEJ\u548cRE\u5df2\u53d1\u8868)\u3002<\/p>\n

\u00a0 \u8be5\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u901a\u8fc7\u7532\u9187\u8fd8\u539f\u5c06\u805a\u4e59\u70ef\uff08PE<\/span>\uff09\u82b3\u6784\u5316\u548c\u5085\u514b\u578b\u70f7\u57fa\u5316\u53cd\u5e94\u76f8\u7ed3\u5408\u7684\u7b56\u7565\uff0c\u5229\u7528\u53cc\u529f\u80fdNiGa\/ZSM-5-H<\/span>\u50ac\u5316\u5242\uff0c\u5728280 \u00b0C<\/span>\u4e0b\u5c06PE<\/span>\u5347\u7ea7\u4e3a\u542b56.1 wt%<\/span>\u82b3\u70c3\u768479.0 wt%<\/span>\u6db2\u4f53\u3002\u5728\u50ac\u5316\u5242\u8bbe\u8ba1\u4e2d\uff0c\u5206\u7ea7\u7ed3\u6784\u7684ZSM-5-H<\/span>\u4fc3\u8fdb\u4e86PE<\/span>\u7684\u88c2\u89e3\uff0c\u800cGa<\/span>\u4e0d\u4ec5\u4f5c\u4e3a\u82b3\u6784\u5316\u548c\u70f7\u57fa\u5316\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u8fd8\u901a\u8fc7\u4eceNi<\/span>\u4e2d\u62bd\u79bb\u7535\u5b50\u5bc6\u5ea6\u6765\u6291\u5236Ni\u2070<\/span>\u7684\u5f62\u6210\uff0c\u4ece\u800c\u786e\u4fddNi\u00b2\u207a<\/span>\u4f5c\u4e3a\u7532\u9187\u8fd8\u539f\u7684\u6d3b\u6027\u50ac\u5316\u4f4d\u70b9\u3002\u6765\u81ea\u805a\u4e59\u70ef\u82b3\u6784\u5316\u7684\u6c22\u7269\u79cd\u53c2\u4e0e\u7532\u9187\u8fd8\u539f\u53cd\u5e94\uff0c\u800c\u7532\u9187\u4e3b\u8981\u4f5c\u4e3a\u6c22\u6e90\u548c\u7532\u57fa\u4f9b\u4f53\uff0c\u4f46\u5728\u53cd\u5e94\u6761\u4ef6\u4e0b\u4e5f\u4f1a\u91ca\u653e\u90e8\u5206\u6c22\uff0c\u4ece\u800c\u4f7f\u805a\u4e59\u70ef\u82b3\u6784\u5316\u548c\u7532\u9187\u8fd8\u539f\u6b65\u9aa4\u5f97\u4ee5\u8026\u5408\u3002\u5728\u6c22\u6c14\u5b58\u5728\u4e0b\uff0c\u7532\u9187\u8fd8\u539f\u4f1a\u751f\u6210\u7532\u57fa\u7269\u79cd\uff0c\u8fd9\u4e9b\u7269\u79cd\u80fd\u4fc3\u8fdb\u5085\u514b\u578b\u70f7\u57fa\u5316\u53cd\u5e94\uff0c\u5c06\u7532\u57fa\u5f15\u5165\u82b3\u9999\u65cf\u5316\u5408\u7269\u7684\u70f7\u57fa\u53d6\u4ee3\u57fa\u4e2d\uff0c\u5e76\u5c06\u00a0C9<\/sub>-C10<\/sub><\/span>\u70f7\u57fa\u82b3\u9999\u65cf\u5316\u5408\u7269\u7684\u6536\u7387\u63d0\u9ad8\u4e86\u00a0600%\u00a0<\/span>\u4ee5\u4e0a\u3002\u901a\u8fc7\u5411PE<\/span>\u50ac\u5316\u5242\u53cd\u5e94\u4f53\u7cfb\u4e2d\u5f15\u51650.99 g\/g<\/span>\u5f53\u91cf\u7684\u7532\u9187\uff0c\u82b3\u70c3\u548cC9<\/sub>-C10<\/sub><\/span>\u70f7\u57fa\u82b3\u70c3\u7684\u6536\u7387\u662f\u672a\u6dfb\u52a0\u7532\u9187\u65f6\u7684\u4e24\u500d\u4ee5\u4e0a\u3002\u8be5\u7b56\u7565\u9002\u7528\u4e8e\u805a\u70ef\u70c3\u7684\u5347\u7ea7\u8f6c\u5316\uff0c\u5e76\u4e3a\u5851\u6599\u5e9f\u5f03\u7269\u7684\u5de5\u4e1a\u5904\u7406\u63d0\u4f9b\u4e86\u4e00\u6761\u5207\u5b9e\u53ef\u884c\u7684\u9014\u5f84\u3002<\/p>\n

\u00a0 \u7ed3\u679c\u53d1\u8868\u5728Angewandte Chemie International Edition<\/span><\/em>\uff1a<\/p>\n

SR Li, RL. Smith, JA Kozinski,\u00a0Zhen Fang*<\/strong>, Coupling Polyolefin Conversion and Methanol Reduction for C9<\/sub>-C10<\/sub>\u00a0Alkylaromatic Production, Angewandte Chemie International Edition,\u00a02026<\/strong>, e5589662,\u00a0https:\/\/doi.org\/10.1002\/anie.5589662<\/a><\/span><\/strong>.<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

Coupling Polyolefin Conversion and Methanol Reduction f […]<\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"_links":{"self":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts\/6459"}],"collection":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/comments?post=6459"}],"version-history":[{"count":1,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts\/6459\/revisions"}],"predecessor-version":[{"id":6461,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts\/6459\/revisions\/6461"}],"wp:attachment":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/media?parent=6459"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/categories?post=6459"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/tags?post=6459"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}