{"id":3621,"date":"2019-01-30T18:46:39","date_gmt":"2019-01-30T10:46:39","guid":{"rendered":"http:\/\/woodrefinery.com\/zhenfang\/?p=3621"},"modified":"2020-09-12T18:01:15","modified_gmt":"2020-09-12T10:01:15","slug":"a-paper-was-accepted-in-nature-communications","status":"publish","type":"post","link":"https:\/\/woodrefinery.com\/zhenfang\/a-paper-was-accepted-in-nature-communications\/","title":{"rendered":"A paper was published in Nature Communications"},"content":{"rendered":"

N-formyl-stabilizing quasi-catalytic species afford rapid and selective solvent-free amination of biomass-derived feedstocks<\/strong><\/p>\n

Recently, Dr. H Li and Prof. Zhen Fang, collaborated with Profs. M Watanabe & RL Smith Jr (Tohoku University, Japan) and Prof. EJM Hensen (Eindhoven University of Technology, The Netherlands), published a paper in Nature Communications<\/strong> about amination of biomass-derived feedstocks.<\/p>\n

Nitrogen-containing compounds, especially primary amines, are vital building blocks in nature and industry. Herein, a protocol is developed that shows in situ formed N-formyl quasi-catalytic species afford highly selective synthesis of formamides or amines with controllable levels from a variety of aldehyde- and ketone-derived platform chemical substrates (that can be easily produced via our patented “fast hydrolysis” process from lignocelluloses and subsequent catalytic conversions) under solvent-free conditions. Up to 99% yields of mono-substituted formamides are obtained in 3\u2009min. The C-N bond formation and N-formyl species are prevalent in the cascade reaction sequence. Kinetic and isotope labeling experiments explicitly demonstrate that the C-N bond is activated for subsequent hydrogenation, in which formic acid acts as acid catalyst, hydrogen donor and as N-formyl species source that stabilize amine intermediates elucidated with density functional theory. The protocol provides access to imides from aldehydes, ketones, carboxylic acids, and mixed-substrates, requires no special catalysts, solvents or techniques and provides new avenues for amination chemistry.<\/p>\n

Related results were published:<\/p>\n

H Li, HX Guo, YQ Su, Y Hiraga, Zhen Fang<\/strong>*, EJM Hensen, M Watanabe* & RL Smith Jr*, N-formyl-stabilizing quasi-catalytic species afford rapid and selective solvent-free amination of biomass-derived feedstocks, Nature Communications<\/u>, 10<\/strong>, Article number: 699 (2019<\/strong>), https:\/\/doi.org\/10.1038\/s41467-019-08577-4<\/a>.<\/p>\n

Behind the paper:<\/p>\n

https:\/\/chemistrycommunity.nature.com\/channels\/1465-behind-the-paper\/posts\/44026-n-formyl-stabilizing-quasi-catalytic-species<\/a><\/p>\n

———————————–<\/p>\n

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2017\u5e74\uff0c\u6211\u4eec\uff08\u65b9\u771f\u6559\u6388\u3001RL Smith Jr\u6559\u6388\u3001\u674e\u864e\u535a\u58eb\uff09\u63d0\u4ea4\u4e86\u4e2d\u56fd\u5357\u4eac\u519c\u4e1a\u5927\u5b66\u548c\u65e5\u672c\u4e1c\u5317\u5927\u5b66\u4e4b\u95f4\u5173\u4e8e\u751f\u7269\u8d28\u751f\u4ea7\u9ad8\u9644\u52a0\u5316\u5b66\u54c1\u7684\u5408\u4f5c\u8ba1\u5212\uff0c\u674e\u864e\u535a\u58eb\u5c06\u5728\u4e1c\u5317\u5927\u5b66\u8fdb\u884c\u4e3a\u671f\u4e24\u5e74\u7684\u535a\u58eb\u540e\u7814\u7a76\u3002\u5728\u51c6\u5907\u8be5\u8ba1\u5212\u65f6\uff0c\u6211\u4eec\u64b0\u5199\u4e86\u4e00\u4efd\u5173\u4e8e\u751f\u7269\u8d28\u7684\u7efc\u8ff0\uff08\u53cc\u529f\u80fd\u56fa\u4f53\u50ac\u5316\u6750\u6599\uff1ahttps:\/\/doi.org\/10.1016\/j.pecs.2016.04.004<\/a>\uff09\u5e76\u51fa\u7248\u4e86\u4e00\u672c\u5173\u4e8e\u53cc\u529f\u80fd\u50ac\u5316\u5242\u7684\u4e66\uff08\u53cc\u529f\u80fd\u50ac\u5316\u5242\u751f\u4ea7\u751f\u7269\u71c3\u6599\u548c\u5316\u5b66\u54c1\uff0cwww.springer.com\/gp\/book\/9789811051364<\/a>\uff09\u3002\u5728\u8fd9\u4e9b\u8c03\u67e5\u4e2d\uff0c\u6211\u4eec\u5f97\u51fa\u7ed3\u8bba\uff0c\u751f\u7269\u8d28\u884d\u751f\u539f\u6599\u7684\u80fa\u5316\u5c06\u662f\u4e00\u4e2a\u5f88\u597d\u7684\u7814\u7a76\u8bfe\u9898\uff0c\u4f46\u5b83\u9700\u8981\u6211\u4eec\u5f00\u53d1\u9ad8\u5ea6\u590d\u6742\u7684\u50ac\u5316\u53cd\u5e94\u7cfb\u7edf\uff0c\u5904\u7406\u6c22\u6c14\u6216\u6c28\uff0c\u5e76\u4ed4\u7ec6\u4f18\u5316\u7ed9\u5b9a\u539f\u6599\u7684\u53cd\u5e94\u6761\u4ef6\u3002\u4f8b\u5982\uff0c\u542b\u6709\u4e00\u4e2a\u4ee5\u4e0a\u5b98\u80fd\u56e2\u7684\u751f\u7269\u8d28\u884d\u751f\u5e73\u53f0\u5316\u5b66\u54c1\uff08\u4f8b\u5982\u544b\u5583\u919b\uff0c\u5982\u7ce0\u919b\uff09\u7684\u80fa\u5316\u4e0d\u6613\u7528\u7ecf\u5178\u6216\u975e\u50ac\u5316\u65b9\u6cd5\u5408\u6210\uff0c\u56e0\u4e3a\u544b\u5583\u73af\u6613\u4e8e\u6253\u5f00\u5f62\u6210\u65e0\u89c4\u6c28\u57fa\u7269\u79cd\u3002\u56e0\u6b64\uff0c\u9700\u8981\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\uff0c\u6700\u7ec8\u5f15\u5bfc\u6211\u4eec\u53d1\u73b0\u4e00\u4e9b\u975e\u5e38\u91cd\u8981\u7684\u5316\u5b66\u53cd\u5e94\u3002<\/p>\n

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\u603b\u800c\u8a00\u4e4b\uff0c\u65e0\u8bba\u662f\u5728\u7814\u7a76\u65b9\u9762\uff0c\u8fd8\u662f\u4e0e\u624d\u534e\u6a2a\u6ea2\u7684\u56fd\u9645\u6210\u5458\u5408\u4f5c\uff0c\u4ee5\u53ca\u4e0e\u81ea\u7136\u7684\u5de5\u4f5c\u4eba\u5458\uff0c\u7f16\u8f91\u548c\u5ba1\u7a3f\u4eba\u5408\u4f5c\uff0c\u70ed\u60c5\u5730\u5e2e\u52a9\u6211\u4eec\u5b9e\u73b0\u5316\u5b66\u7684\u6f5c\u529b\uff0c\u8fd9\u90fd\u662f\u4e00\u6bb5\u7f8e\u5999\u7684\u65c5\u7a0b\u3002\u6709\u5173\u5b8c\u6574\u8bc4\u8bba\u8005\u7684\u8bc4\u8bba\u548c\u4f5c\u8005\u56de\u590d\uff0c\u8bf7\u53c2https:\/\/rdcu.be\/bma7w<\/a> \u548c\u652f\u6301\u6750\u6599\u3002\u6709\u5173\u8be6\u7ec6\u4fe1\u606f\uff0c\u8bf7\u53c2\u9605\u6211\u4eec\u7684\u8bba\u6587\uff1a<\/p>\n

H Li, HX Guo, YQ Su, Y Hiraga, Zhen Fang<\/strong>*, EJM Hensen, M Watanabe* & RL Smith Jr*, N-formyl-stabilizing quasi-catalytic species afford rapid and selective solvent-free amination of biomass-derived feedstocks, Nature Communications<\/u>, 10<\/strong>, Article number: 699 (2019<\/strong>), https:\/\/doi.org\/10.1038\/s41467-019-08577-4<\/a>.<\/p>\n","protected":false},"excerpt":{"rendered":"

N-formyl-stabilizing quasi-catalytic species afford rap […]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"_links":{"self":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts\/3621"}],"collection":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/comments?post=3621"}],"version-history":[{"count":11,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts\/3621\/revisions"}],"predecessor-version":[{"id":4082,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts\/3621\/revisions\/4082"}],"wp:attachment":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/media?parent=3621"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/categories?post=3621"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/tags?post=3621"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}