{"id":3179,"date":"2017-08-06T15:51:55","date_gmt":"2017-08-06T07:51:55","guid":{"rendered":"http:\/\/woodrefinery.com\/zhenfang\/?p=3179"},"modified":"2017-08-21T16:55:53","modified_gmt":"2017-08-21T08:55:53","slug":"springer-book-production-of-platform-chemicals-from-sustainable-resources-published","status":"publish","type":"post","link":"https:\/\/woodrefinery.com\/zhenfang\/springer-book-production-of-platform-chemicals-from-sustainable-resources-published\/","title":{"rendered":"Hydrophobic Pd nanocatalysts for one-pot and high-yield production of liquid furanic biofuels at low temperatures"},"content":{"rendered":"<p style=\"text-align: justify;\"><strong>Hydrophobic Pd nanocatalysts for one-pot and high-yield production of liquid furanic biofuels at low temperatures<\/strong><\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-3189\" src=\"https:\/\/woodrefinery.com\/zhenfang\/wp-content\/uploads\/2017\/08\/2017-8-20news-report-ACB-huLi.jpg\" alt=\"\" width=\"350\" height=\"248\" srcset=\"https:\/\/woodrefinery.com\/zhenfang\/wp-content\/uploads\/2017\/08\/2017-8-20news-report-ACB-huLi.jpg 957w, https:\/\/woodrefinery.com\/zhenfang\/wp-content\/uploads\/2017\/08\/2017-8-20news-report-ACB-huLi-300x213.jpg 300w, https:\/\/woodrefinery.com\/zhenfang\/wp-content\/uploads\/2017\/08\/2017-8-20news-report-ACB-huLi-768x545.jpg 768w\" sizes=\"(max-width: 350px) 100vw, 350px\" \/><\/p>\n<p style=\"text-align: justify;\">Efficient production of furanic\/aromatic hydrocarbons (&gt;95% yields) from biomass derivatives is achieved via a single-step process under mild conditions (25-130 \u00baC) by using readily available polymethylhydrosiloxane as liquid H-donor over hydrophonic Pd nanoparticles on MOFs.\u3010\u4ee5\u805a\u7532\u57fa\u6c22\u7845\u6c27\u70f7\u4e3a\u6c22\u6e90\uff0c\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b (25-130 \u00baC)\uff0c\u5229\u7528\u758f\u6c34\u7eb3\u7c73\u94afPd\u50ac\u5316\u7cd6\u7c7b\uff08\u7fb0\u57fa\u548c\u7f9f\u57fa\u5316\u7269\uff09\uff0c\u4e00\u9505\u9ad8\u6548(&gt; 95% \u4ea7\u91cf)\u5408\u6210\u544b\u5583\u6db2\u4f53\u71c3\u6599\u3011<\/p>\n<p style=\"text-align: justify;\">\u00a0Recently, Dr. Hu Li supervised by Prof. Zhen FANG has developed a single-step catalytic process for direct conversion of various saccharides to produce furanic biofuels such as 2,5-dimethylfuran and 2-methylfuran with high yields (&gt; 95%) at 110-130 \u00baC. The negatively charged hydride (H-) of readily available polymethylhydrosiloxane (PMHS) acting as green H-donor over hydrophobic Pd nanoparticles did not obstruct upstream reactions (e.g., hydrolysis, isomerization and dehydration) for the in situ formation of furanic aldehydes\/alcohols from sugars, and could selectively facilitate the subsequent hydrodeoxygenation of carbonyl and hydroxyl groups other than the furanic ring in one pot, as clarified by deuterium-labeling study. Importantly, the unreduced Pd(II) catalysts also exhibited comparable performance in the selective hydrodeoxygenation reaction. Moreover, the catalytic strategy was extended to various carboxides for quantitative production of corresponding furanic\/aromatic hydrocarbons at room temperature that were more pronounced than previously reported results, and the optimal Pd\/MIL-53(Al) coated with polydimethylsiloxane (Pd\/MIL-53(Al)-P) was highly stable with little deactivation and Pd leaching for at least five consecutive cycles.<br \/>\n<strong>Related results were published:<\/strong><br \/>\n1.H Li, W Zhao, Zhen Fang*, Hydrophobic Pd Nanocatalysts for One-Pot and High-Yield Production of Liquid Furanic Biofuels at Low Temperatures, <strong>Applied Catalysis B: Environmental<\/strong>, 215, 18\u201327 (2017).<br \/>\n2.H Li, W Zhao, A Riisager, S Saravanamurugan*, Z Wang, Zhen Fang*, S Yang*, Pd-catalyzed in-situ domino process for mild and quantitative production of 2,5-dimethylfuran directly from carbohydrates,\u00a0 <strong>Green Chemistry<\/strong>, 19, 2101\u20132106 (2017).<br \/>\n&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8212;&#8211;<br \/>\n<strong>\u9ad8\u6548\u4f4e\u6e29\u4ece\u7cd6\u548c\u7fb0\u57fa\u5316\u7269\u4e00\u6b65\u76f4\u63a5\u5408\u6210\u544b\u5583\u6db2\u4f53\u71c3\u6599<\/strong><\/p>\n<p style=\"text-align: justify;\">\u6700\u8fd1\uff0c\u56fd\u9645\u5b66\u672f\u671f\u520aApplied Catalysis B: Environmental\uff08\u5f71\u54cd\u56e0\u5b509.4\uff0c\u7b2c\u4e00\u7f72\u540d\u5355\u4f4d\u4e3a\u5357\u4eac\u519c\u4e1a\u5927\u5b66\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u535a\u58eb\u540e\u674e\u864e\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u65b9\u771f\u6559\u6388\uff09\u53caGreen Chemistry \u3010\u5f71\u54cd\u56e0\u5b509.2\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u674e\u864e\u535a\u58eb\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u6768\u677e\u6559\u6388\uff08\u8d35\u5dde\u5927\u5b66\uff09\uff0cSaravanamurugan\u535a\u58eb\uff08\u5370\u5ea6\uff09\u548c\u65b9\u771f\u6559\u6388\u3011\uff0c\u53d1\u8868\u4e86\u751f\u7269\u71c3\u6599\u6700\u65b0\u7814\u7a76\u6210\u679c\u3002<br \/>\n\u8be5\u7814\u7a76\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u4e2a\u5355\u6b65\u50ac\u5316\u8fc7\u7a0b, \u4ee5\u805a\u7532\u57fa\u6c22\u7845\u6c27\u70f7polymethylhydrosiloxane (PMHS)\u4e3a\u6c22\u6e90\uff0c\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b (25-130 \u00baC)\uff0c\u5229\u7528\u758f\u6c34\u7eb3\u7c73\u94af\uff08Pd\uff09\u50ac\u5316\u7cd6\u7c7b\uff08\u7fb0\u57fa\u548c\u7f9f\u57fa\u5316\u7269\uff09\uff0c\u5355\u6b65\u9ad8\u6548(&gt; 95% \u4ea7\u91cf)\u5408\u6210\u544b\u5583\u6db2\u4f53\u71c3\u6599\u3002<br \/>\n\u4ed6\u4eec\u53d1\u73b0PMHS\uff08\u5e26\u8d1f\u7535\u8377\u7684\u9ad8\u5206\u5b50\u6c22\u5316\u7269\uff09\uff0c\u4f5c\u4e3a\u7eff\u8272\u6c22\u6e90\uff0c\u4ee5\u7eb3\u7c73\u94af\u4e3a\u50ac\u5316\u5242\uff0c\u5728\u539f\u4f4d\u52a0\u6c22\u7cd6\u7c7b\u5408\u6210\u544b\u5583\u919b\/\u9187\u65f6\uff0c\u4e0d\u4f1a\u963b\u788d\u5176\u4e0a\u6e38\u7684\u53cd\u5e94 (\u4f8b\u5982, \u6c34\u89e3, \u5f02\u6784\u5316\u548c\u8131\u6c34)\u3002\u901a\u8fc7\u540c\u4f4d\u7d20\u6c18\u6807\u8bb0\u7814\u7a76\u8bc1\u660e\uff0c\u8be5\u53cd\u5e94\u7cfb\u7edf\u53ef\u4ee5\u4e00\u9505\u6cd5\uff0c\u6709\u9009\u62e9\u5730\u4fc3\u8fdb\u7fb0\u57fa\u548c\u7f9f\u57fa\u5316\u7269\u7684\u52a0\u6c22\u8131\u6c27\u3002\u66f4\u91cd\u8981\u7684\u662f, \u672a\u8fd8\u539f\u7684Pd(II)\u7eb3\u7c73\u50ac\u5316\u5242\u5728\u9009\u62e9\u6027\u52a0\u6c22\u8131\u6c27\u53cd\u5e94\u4e2d\u4e5f\u8868\u73b0\u51fa\u76f8\u5f53\u7684\u6027\u80fd\u3002\u6b64\u5916, \u5f53\u8be5\u50ac\u5316\u53cd\u5e94\u7cfb\u7edf\u6269\u5c55\u5230\u5229\u7528\u5404\u79cd\u7fb0\u57fa\u5316\u7269\u65f6, \u53ef\u5728\u5ba4\u6e29\u4e0b\uff0c\u5b9a\u91cf\u751f\u4ea7\u76f8\u5e94\u7684\u544b\u5583\/\u82b3\u70c3\u3002\u7528\u805a\u4e8c\u7532\u57fa\u7845\u6c27\u70f7\u6d82\u5c42\u7684\u758f\u6c34Pd\u50ac\u5316\u5242\u5177\u6709\u6781\u9ad8\u7684\u7a33\u5b9a\u6027, \u4e14\u5728\u81f3\u5c11\u8fde\u7eed\u4e94\u4e2a\u5468\u671f\u4e2d\u51e0\u4e4e\u6ca1\u6709\u5931\u6d3b\u548cPd\u6d78\u51fa\u3002<\/p>\n<p style=\"text-align: justify;\"><strong>\u8be6\u60c5\u53ef\u89c1\uff1a<\/strong><br \/>\n1.H Li, W Zhao, Zhen Fang*, Hydrophobic Pd Nanocatalysts for One-Pot and High-Yield Production of Liquid Furanic Biofuels at Low Temperatures, <strong>Applied Catalysis B: Environmental<\/strong>, 215, 18\u201327 (2017).<br \/>\n2.H Li, W Zhao, A Riisager, S Saravanamurugan*, Z Wang, Zhen Fang*, S Yang*, Pd-catalyzed in-situ domino process for mild and quantitative production of 2,5-dimethylfuran directly from carbohydrates,\u00a0 <strong>Green Chemistry<\/strong>, 19, 2101\u20132106 (2017).<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Hydrophobic Pd nanocatalysts for one-pot and high-yield [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"_links":{"self":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts\/3179"}],"collection":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/comments?post=3179"}],"version-history":[{"count":3,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts\/3179\/revisions"}],"predecessor-version":[{"id":3190,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/posts\/3179\/revisions\/3190"}],"wp:attachment":[{"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/media?parent=3179"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/categories?post=3179"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/woodrefinery.com\/zhenfang\/wp-json\/wp\/v2\/tags?post=3179"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}